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dc.contributor.authorHernández, Yohar A.-
dc.contributor.authorLópez-Serrano, Joaquín-
dc.contributor.authorPaneque, Margarita-
dc.contributor.authorPoveda, Manuel L.-
dc.contributor.authorVattier, Florencia-
dc.contributor.authorSalazar, Verónica-
dc.contributor.authorÁlvarez, Eleuterio-
dc.contributor.authorCarmona, Ernesto-
dc.date.accessioned2013-04-01T14:28:27Z-
dc.date.available2013-04-01T14:28:27Z-
dc.date.issued2011-
dc.identifierissn: 0947-6539-
dc.identifier.citationChemistry - A European Journal 17: 9302- 9305 (2011)-
dc.identifier.urihttp://hdl.handle.net/10261/73291-
dc.description.abstractH,D pick and mix: The pyridylidene compounds [TpIr(C6H5) (CN(H) C4(R)H3)] (R=H, Me, and Ph) react with O2 to form mixtures of two complexes (see scheme). One of them, 4, contains a newly formed CN bond as the result of an oxidative dehydrogenation. During a mechanistic study on its formation, an unexpected H,D scrambling has been disclosed.-
dc.language.isoeng-
dc.publisherWiley-VCH-
dc.rightsclosedAccess-
dc.titleC-N bond formation by O2-mediated dehydrogenative coupling of phenyl and NH-pyridylidene ligands on TpMe2 Irlll complexes-
dc.typeartículo-
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201101276-
dc.date.updated2013-04-01T14:28:27Z-
dc.description.versionPeer Reviewed-
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