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C-N bond formation by O2-mediated dehydrogenative coupling of phenyl and NH-pyridylidene ligands on TpMe2 Irlll complexes

AuthorsHernández, Yohar A.; López-Serrano, Joaquín ; Paneque, Margarita ; Poveda, Manuel L.; Vattier, Florencia ; Salazar, Verónica; Álvarez, Eleuterio ; Carmona, Ernesto
Issue Date2011
CitationChemistry - A European Journal 17: 9302- 9305 (2011)
AbstractH,D pick and mix: The pyridylidene compounds [TpIr(C6H5) (CN(H) C4(R)H3)] (R=H, Me, and Ph) react with O2 to form mixtures of two complexes (see scheme). One of them, 4, contains a newly formed CN bond as the result of an oxidative dehydrogenation. During a mechanistic study on its formation, an unexpected H,D scrambling has been disclosed.
Identifiersissn: 0947-6539
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