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Study of the electronic-to-vibrational energy transfer in the quenching process of Na*(3 2P) with N2(1Σ + g,v=0). A quantal close coupling calculation

AuthorsCampos-Martínez, José ; Roncero, Octavio ; Miret-Artés, Salvador ; Villarreal, Pablo ; Delgado Barrio, Gerardo
Issue Date1989
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 91: 155- 161 (1989)
AbstractElectronic-to-vibrational energy transfer has been studied by solving numerically the close-coupling equations, in the T-shape configuration, on the two lowest electronic states of the Na-N2 system. The diabatic potential surfaces were taken from Archirel and Habitz while the interelectronic coupling was modeled by different Gaussian-type functions. Different sets of parameters for the coupling were used in order to study the final vibrational distributions of N2. Finally, partial quenching probabilities are presented and compared with previous theoretical and experimental works. © 1989 American Institute of Physics.
Identifiersdoi: 10.1063/1.457494
issn: 0021-9606
Appears in Collections:(CFMAC-IEM) Artículos
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