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Título: | Structural characterization of lignin isolated from coconut (Cocos nucifera) coir fibers |
Autor: | Rencoret, Jorge CSIC ORCID; Ralph, John; Marques, Gisela CSIC ORCID; Gutiérrez Suárez, Ana CSIC ORCID ; Martínez, Ángel T. CSIC ORCID ; Río Andrade, José Carlos del CSIC ORCID | Palabras clave: | Coconut Coir Lignin Py-GC/MS TMAH HSQC DFRC Thioacidolysis P-hydroxybenzoates Tricin |
Fecha de publicación: | 2013 | Editor: | American Chemical Society | Citación: | Journal of Agricultural and Food Chemistry 61: 2434-2445 (2013) | Resumen: | The structure of the isolated milled “wood” lignin from coconut coir has been characterized using different analytical methods, including Py-GC/MS, 2D NMR, DFRC, and thioacidolysis. The analyses demonstrated that it is a phydroxyphenyl-guaiacyl-syringyl (H-G-S) lignin, with a predominance of G units (S/G ratio 0.23) and considerable amounts of associated p-hydroxybenzoates. Two-dimensional NMR indicated that the main substructures present in this lignin include β−O−4′ alkyl aryl ethers followed by phenylcoumarans and resinols. Two-dimensional NMR spectra also indicated that coir lignin is partially acylated at the γ-carbon of the side chain with p-hydroxybenzoates and acetates. DFRC analysis showed that acetates preferentially acylate the γ−OH in S rather than in G units. Despite coir lignin’s being highly enriched in G-units, thioacidolysis indicated that β−β′ resinol structures are mostly derived from sinapyl alcohol. Finally, we find evidence that the flavone tricin is incorporated into the coconut coir lignin, as has been recently noted for various grasses. | Descripción: | 12 pages, 6 figures, 7 tables, 60 references. †Instituto de Recursos Naturales y Agrobiología de Sevilla (IRNAS), CSIC, PO Box 1052, E-41080 Seville, Spain ‡Departments of Biochemistry and Biological Systems Engineering, the Wisconsin Energy Institute, and the DOE Great Lakes Bioenergy Research Center, University of Wisconsin, Madison, Wisconsin 53726, United States §Centro de Investigaciones Biológicas (CIB), CSIC, Ramiro de Maeztu 9, E-28040 Madrid, Spain | Versión del editor: | http://dx.doi.org/10.1021/jf304686x | URI: | http://hdl.handle.net/10261/72136 | DOI: | 10.1021/jf304686x | ISSN: | 0021-8561 | E-ISSN: | 1520-5118 |
Aparece en las colecciones: | (IRNAS) Artículos (CIB) Artículos |
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Structural characterization of lignin isolated from coconut.pdf | 1,36 MB | Adobe PDF | Visualizar/Abrir |
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