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Title

Anharmonicity effects on the vibrational predissociation of the NeI2(B 3Πu +, ν) complex: A close-coupling infinite-order sudden treatment

AuthorsRoncero, Octavio ; Campos-Martínez, José ; Cortina, A. M.; Villarreal, Pablo ; Delgado Barrio, Gerardo
Issue Date1988
PublisherElsevier
CitationChemical Physics Letters 148: 62- 67 (1988)
AbstractA model previously applied to study the vibrational predissociation (VP) of HeI2(B, ν) is extended to treat the VP of NeI2(B, ν) in the region of initial vibrational excitation 28≤ν≤34. Due to the anharmonicity of the diatomic subunit, the usually predominant channel for VP, Δν=-1, becomes energetically forbidden. This gives rise to oscillations of the VP rate as a function of ν that no longer follows the typical superlinear behaviour shown in the low diatomic excitation regime. © 1988.
URIhttp://hdl.handle.net/10261/71494
DOI10.1016/0009-2614(88)87261-0
Identifiersdoi: 10.1016/0009-2614(88)87261-0
issn: 0009-2614
Appears in Collections:(CFMAC-IEM) Artículos
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