English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/66498
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

A computational study of the effect of C-lithiation on the NMR properties (chemical shifts and coupling constants) of aziridines

AuthorsCapriati, V.; Florio, S.; Luisi, R.; Musio, B.; Alkorta, Ibon ; Blanco, Fernando; Elguero, José
Issue Date2008
PublisherKluwer Academic Publishers
CitationStructural Chemistry 19: 785- 792 (2008)
AbstractA DFT (B3LYP/6-311++G(d,p) study of a series of N-H, N-methyl and N-propyl aziridines and their C-lithium derivatives has been carried out in order to explore their configurational as well as their NMR properties (1H and 13C). The results agree fairly well with experimental observations [Org Lett 9:1263, 2007 and J Org Chem 73, 2008 (73:3197)] and reveal the existence of lithium-N(lone pair) and lithium C(aromatic) interactions. © 2008 Springer Science+Business Media, LLC.
Publisher version (URL)http://dx.doi.org/10.1007/s11224-008-9365-0
URIhttp://hdl.handle.net/10261/66498
DOI10.1007/s11224-008-9365-0
Identifiersdoi: 10.1007/s11224-008-9365-0
issn: 1040-0400
e-issn: 1572-9001
Appears in Collections:(IQM) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.