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Trans additions of silanes to 1-alkynes catalyzed by ruthenium complexes: Role of in situ formed polynuclear aggregates

AuthorsMartín, Marta ; Sola, Eduardo ; Lahoz, Fernando J. ; Oro, Luis A.
Issue Date2002
PublisherAmerican Chemical Society
CitationOrganometallics 21(20): 4027-4029 (2002)
Abstract(Z)-Alkenyl ligands are formed by insertion of 1-alkynes into bridging hydrides. The unusual stereoselectivity of this elementary step may account for the selectivity toward (Z)-alkenylsilanes frequently observed in 1-alkyne hydrosilylations catalyzed by basic late-transition-metal complexes.
Identifiersdoi: 10.1021/om0205243
issn: 0276-7333
e-issn: 1520-6041
Appears in Collections:(ICMA) Artículos
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