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The dehydrogenation of alcohols through a concerted bimetallic mechanism involving an amido-bridged diiridium complex

AuthorsMena, Inmaculada ; Casado, Miguel A. ; Polo, Víctor; García-Orduña, P. ; Lahoz, Fernando J. ; Oro, Luis A.
Issue Date2012
CitationAngewandte Chemie International Edition 51(33): 8259-8263 (2012)
AbstractFrom amido to imido: A dinuclear amido-bridged iridium complex promotes the dehydrogenation of alcohols, affording unusual mixed amido/imido Ir 4 and bis(imido) Ir 3 clusters. Theoretical calculations suggest that bridging μ-NH 2 linkages are crucial to achieve the formation of hydrido amine diiridium species, as a result of a concerted net hydrogen transfer through a proposed eight-membered dimetallacycle. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/anie.201202936
Identifiersdoi: 10.1002/anie.201202936
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ISQCH) Artículos
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