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| Título: | Synthesis and characterization of IrH2{Si(OTf)Ph2}(TFB)(PR3) (PR3 = PiPr3, PCy3): First base-stabilized silylene complexes of iridium |
Autor: | Chen, Wanzhi; Esteruelas, Miguel A. CSIC ORCID; Lahoz, Fernando J. CSIC ORCID; Oliván, Montserrat CSIC ORCID ; Oro, Luis A. CSIC ORCID | Fecha de publicación: | 1996 | Editor: | American Chemical Society | Citación: | Organometallics 15(8): 2185-2188 (1996) | Resumen: | The reactions of H2SiPh2 with the triflato complexes Ir(OTf)(TFB)(PR3) afford the base-stabilized silylene complexes IrH2{Si(OTf)Ph2}(TFB)(PR3) (TFB = tetrafluorobenzobarrelene; PR3 = PiPr3, PCy3). The single-crystal X-ray structural analysis of IrH2{Si(OTf)-Ph2}(TFB)(PiPr3) has been performed. The distances Ir-Si (2.337(2) Å) and Si-O (1.790(5) Å) as well as the summation of angles at silicon, ignoring the Si-OTf bond (343.5°), are in agreement with the partial unsaturated character of the base-stabilized silylene ligand. | URI: | http://hdl.handle.net/10261/65145 | DOI: | 10.1021/om9508896 | Identificadores: | doi: 10.1021/om9508896 issn: 0276-7333 e-issn: 1520-604 |
| Aparece en las colecciones: | (ICMA) Artículos |
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| accesoRestringido.pdf | 15,38 kB | Adobe PDF |  Visualizar/Abrir |
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