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Surface-enhanced stereoselectivity in Mukaiyama aldol reactions catalyzed by clay-supported bis(oxazoline)-copper complexes

AuthorsFabra-Caro, María J.; Fraile, José M. ; Herrerías, Clara I. ; Lahoz, Fernando J. ; Mayoral, José A. ; Pérez, Ignacio
Issue Date2008
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 42: 5402-5404 (2008)
AbstractSurface effects on a laponite-exchanged bis(oxazoline)-copper complex modify the stereochemical course of the Mukaiyama aldol reaction between 2-(trimethylsilyloxy)furan and α-ketoesters, leading up to 90% ee (dr 86: 14) becoming the best overall result obtained for this reaction and significantly improving the homogeneous process. © The Royal Society of Chemistry.
Identifiersdoi: 10.1039/B809956A
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(ICMA) Artículos
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