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Sequential C−H activation and dinuclear insertion of ethylene promoted by a diiridium complex

AuthorsJiménez, M. Victoria ; Sola, Eduardo ; Lahoz, Fernando J. ; Oro, Luis A.
Issue Date2002
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 124(5): 752-753 (2002)
AbstractTwo ethylene molecules, bonded to different metal atoms of a diiridium(I) complex, can be converted into a bridging 3-butenyl-1-yl ligand and a terminal hydride. Such transformation is initiated by an ethylene C-H activation step and followed by an insertion of the second ethylene into a bridging vinyl ligand. This result illustrates the potentiality of diiridium(I) complexes to promote and support reaction sequences of alkene functionalization through C-H activation. Copyright © 2002 American Chemical Society.
Identifiersdoi: 10.1021/ja016753i
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ICMA) Artículos
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