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dc.contributor.author | Esteruelas, Miguel A. | - |
dc.contributor.author | Fernández-Álvarez, Francisco J. | - |
dc.contributor.author | Oliván, Montserrat | - |
dc.contributor.author | Oñate, Enrique | - |
dc.date.accessioned | 2013-01-23T12:51:35Z | - |
dc.date.available | 2013-01-23T12:51:35Z | - |
dc.date.issued | 2009 | - |
dc.identifier | doi: 10.1021/om8011954 | - |
dc.identifier | issn: 0276-7333 | - |
dc.identifier | e-issn: 1520-6041 | - |
dc.identifier.citation | Organometallics 28(7): 2276-2284 (2009) | - |
dc.identifier.uri | http://hdl.handle.net/10261/64866 | - |
dc.description.abstract | The reactions of the indium complexes IrHCl2(P iPr3)2 (1) and IrCl(η2-C 8H14)(PiPr3)2 (2) with quinoline, 8-methylquinoline, 2-methylpyridine and benzo[h]quinoline (Hbq) have been studied. Complex 1 promotes the NH-tautomerization of quinoline and 8-methylquinoline and stabilizes the resulting NH-tautomers to afford IrHCl 2{κ-C-(HNC9H6)}(PiPr 3)2 (3) and IrHCl2{κ-C-(HNC 9H5CH3)}(PiPr3) 2 (4), while the respective reactions of 2 lead to IrH{CH 2CH(CH3)PiPr2}Cl{κ-N-(NC 9H7)}(PiPr3) (5) and IrHCl(CH 2C9H6N)(PiPr3) 2 (6). Complex 1 also tautomerizes 2-methylpyridine and stabilizes the resulting tautomer to give IrHCl2{κ-C-(HNC 5H3CH3)}(PiPr3) 2 (7). However, in the presence of 2, the tautomerization does not occur. Treatment of 2 with 2-methylpyridine leads to a mixture of unidentified nontautomer derivatives. The products from the reactions of 1 with benzo[h]quinoline depend upon the metal/heterocycle ratios used. Treatment of 1 with 1,2 equiv of benzo[h]quinoline leads to the NH-tautomer derivative IrHCl2{κ-C-(HNbq)}(PiPr3)2 (8; 15) and the metalated species IrHCl{κ-N,C-(bq)}(PiPr 3)2 (9; 85). However, when a 1:3 molar ratio is used, 9 (60) and the salt [HNHbq][IrHCl3(PiPr3) 2] (10, 40%; HNHbq = benzo[ft]quinolinium) are formed. Complexes 4, 5, 6, 7, 9, and 10 have been characterized by X-ray diffraction analysis. The mechanism of the NH-tautomeration is also reported. © 2009 American Chemical Society. | - |
dc.description.sponsorship | Financial support from the MICINN of Spain (project number CTQ2008-00810 and Consolider Ingenio 2010 CSD2007-00006) and the Diputación General de Aragón (E35) is acknowledged. | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.rights | closedAccess | - |
dc.title | NH-tautomerization of quinolines and 2-methylpyridine promoted by a hydride-iridium(III) complex: Importance of the hydride ligand | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/om8011954 | - |
dc.date.updated | 2013-01-23T12:51:35Z | - |
dc.description.version | Peer Reviewed | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
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