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Title

Nazarov type cyclization on an osmium-dienylcarbene complex

AuthorsBolaño, Tamara ; Castarlenas, Ricardo ; Esteruelas, Miguel A. ; Oñate, Enrique
Issue Date2009
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 131(6): 2064-2065 (2009)
AbstractThe presence of carbon monoxide in the dienylcarbene complex [Os{=C(CH=CHPh)(CH=CPh2)}(CO)(CH3CN)2(PiPr3) 2][BF4]2 promotes a 4# conrotation of the dienylcarbene to afford [Os(=CCH2CPh2CPh=CH)(CO)(CH 3CN)2(PiPr3)2][BF4] 2 containing a cyclic alkenylcarbene ligand, via the (1-cyclopentadienyl intermediate [Os(C=CHCPh2CPh=CH)(CO)=(CH 3CN)2(PiPr3)2]BF4. Copyright © 2009 American Chemical Society.
URIhttp://hdl.handle.net/10261/64843
DOI10.1021/ja8093058
Identifiersdoi: 10.1021/ja8093058
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ICMA) Artículos
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