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Influence of the solvent in the synthesis of osmium complexes containing cyclopentadienyl ligands with a pendant donor group

AuthorsEsteruelas, Miguel A. ; López, Ana M. ; Oñate, Enrique ; Royo, Eva
Issue Date2004
PublisherAmerican Chemical Society
CitationOrganometallics 23(23): 5633-5636 (2004)
AbstractThe course of the reactions between complex OsH2Cl 2(PiPr3) (1) and the functionalized cyclopentadienyllithium derivatives Li(C55H4CH 2)2E (E = NMe2 (2), OMe (3)) strongly depends on the solvent used. Thus, in the presence of donor solvents such as THF, the salts [OsH2{η5-C5H4(CH 2)2E}(PiPr3)2] [(OsHCl2(CO)(PiPr3)2](E = NMe 2 [4][5], OMe [6][5]) with a carbonylated osmium anion are produced, while in hydrocarbon solvents the chloride salts [OsH2{n 5-C5H4(CH2)2E}(P iPr3)2]Cl (E = NMe2 [4]Cl, OMe [6]Cl) are formed.
Identifiersdoi: 10.1021/om049514n
issn: 0276-7333
e-issn: 1520-6041
Appears in Collections:(ICMA) Artículos
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