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Formation of unusual iridabenzene and metallanaphthalene containing electron-withdrawing substituents

AuthorsPaneque, Margarita ; Posadas, Cristina M.; Poveda, Manuel L.; Rendón, Nuria ; Salazar, Verónica; Oñate, Enrique ; Mereiter, Kurt
Issue Date2003
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 125(33): 9898-9899 (2003)
AbstractA new route to irida-aromatic derivatives which consists of the oxidation of bicyclic compounds has been disclosed. The iridanaphthalene 3 experiences hydrolytic cleavage of the Ir-carboxylate moiety regenerating the bicyclic structure 5, whereas treatment of 5 with ClC(O)CO2Me yields back the metalla-aromatic 3. Copyright © 2003 American Chemical Society.
Identifiersdoi: 10.1021/ja035655p
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ICMA) Artículos
(IIQ) Artículos
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