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Enantioselective catalysis with chiral complexes immobilized on nanostructured supports

AuthorsFraile, José M. ; García, José I. ; Herrerías, Clara I. ; Mayoral, José A. ; Pires, Elísabet
Issue Date2009
PublisherRoyal Society of Chemistry (UK)
CitationChemical Society Reviews 38(3): 695-706 (2009)
AbstractIn this tutorial review, we discuss how recycling and stability advantages alone are frequently not sufficient to justify the effort necessary to immobilize chiral complexes unless additional advantages are found. Nanostructured solids with well-controlled surfaces and pores may act as nanoreactors, hindering or even blocking some of the reaction channels, and hence modifying the stereochemical result of the reaction. The use of support effects to improve or change the enantioselectivity is emerging as an interesting field, whose understanding might allow, in the near future, the design of chiral ligands better adapted to this strategy. © 2009 The Royal Society of Chemistry.
DescriptionEl pdf del artículo es la versión post-print.
Publisher version (URL)http://dx.doi.org/10.1039/B806643B
Identifiersdoi: 10.1039/B806643B
issn: 0306-0012
e-issn: 1460-4744
Appears in Collections:(ICMA) Artículos
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