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Title

Effective fixation of CO2 by iridium-catalyzed hydrosilylation

AuthorsLalrempuia, Ralte ; Iglesias, Manuel ; Polo, Víctor; Sanz Miguel, Pablo J. ; Fernández-Álvarez, Francisco J. ; Pérez-Torrente, Jesús J. ; Oro, Luis A.
Issue Date2012
PublisherWiley-VCH
CitationAngewandte Chemie International Edition 51(51): 12824-12827 (2012)
AbstractCO2 as feedstock: An air- and moisture-stable iridium(III) catalyst effectively promotes the hydrosilylation of CO2. This reaction leads to silyl formate in a highly selective manner and proceeds efficiently under mild conditions, most likely by an outer-sphere mechanism, as suggested by theoretical calculations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/anie.201206165
URIhttp://hdl.handle.net/10261/64582
DOI10.1002/anie.201206165
Identifiersissn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ISQCH) Artículos
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