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Title

Direct access to parent amido complexes of rhodium and iridium through N-H activation of ammonia

AuthorsMena, Inmaculada ; Casado, Miguel A. ; García-Orduña, P. ; Polo, Víctor; Lahoz, Fernando J. ; Fazal, Atif; Oro, Luis A.
Issue Date2011
PublisherWiley-VCH
CitationAngewandte Chemie International Edition 50(49): 11735-11738 (2011)
AbstractSimplicity! A direct entry to amido rhodium and iridium complexes was easily achieved by reaction of gaseous ammonia with alkoxo-bridged precursors under very mild conditions. This new approach allowed the high-yield access for the first time to elusive [Rh-NH 2] complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publisher version (URL)http://dx.doi.org/10.1002/anie.201104745
URIhttp://hdl.handle.net/10261/64560
DOI10.1002/anie.201104745
Identifiersdoi: 10.1002/anie.201104745
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ISQCH) Artículos
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