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Dioxygen Activation by an Osmium-dihydride: Preparation and Characterization of a d4 Square-Planar Complex

AuthorsEsteruelas, Miguel A. ; Modrego, Francisco J. ; Oñate, Enrique ; Royo, Eva
Issue Date2003
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 125(44): 13344-13345 (2003)
AbstractExposure of OsH2Cl2(PiPr3)2 to air or bubbling with pure O2 affords the dioxo-Os(VI) compound OsO2Cl2(PiPr3)2 as result of a direct O=O double bond activation reaction. This Os(VI) species is reduced in the presence of n-BuLi to the novel dioxo-Os(IV) derivative OsO2(PiPr3)2, a rare example of a d4 square-planar compound. Copyright © 2003 American Chemical Society.
Identifiersdoi: 10.1021/ja037484u
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ICMA) Artículos
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