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| Title: | Dioxygen Activation by an Osmium-dihydride: Preparation and Characterization of a d4 Square-Planar Complex |
| Authors: | Esteruelas, Miguel A.  ; Modrego, Francisco J. ; Oñate, Enrique ; Royo, Eva |
| Issue Date: | 2003 |
| Publisher: | American Chemical Society |
| Citation: | Journal of the American Chemical Society 125(44): 13344-13345 (2003) |
| Abstract: | Exposure of OsH2Cl2(PiPr3)2 to air or bubbling with pure O2 affords the dioxo-Os(VI) compound OsO2Cl2(PiPr3)2 as result of a direct O=O double bond activation reaction. This Os(VI) species is reduced in the presence of n-BuLi to the novel dioxo-Os(IV) derivative OsO2(PiPr3)2, a rare example of a d4 square-planar compound. Copyright © 2003 American Chemical Society. |
| URI: | http://hdl.handle.net/10261/64556 |
| DOI: | 10.1021/ja037484u |
| Identifiers: | doi: 10.1021/ja037484u issn: 0002-7863 e-issn: 1520-5126 |
| Appears in Collections: | (ICMA) Artículos |
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| accesoRestringido.pdf | 15,38 kB | Adobe PDF |  View/Open |
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