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Dehalogenation of polychloroarenes with sodium formate in propan-2-ol catalyzed by RhCl(PPh3)3

AuthorsEsteruelas, Miguel A. ; Herrero, Juana; Oliván, Montserrat
Issue Date2001
PublisherRoyal Society of Chemistry (UK)
CitationNew Journal of Chemistry 25(6): 775-776 (2001)
AbstractPolychloroarenes can be dehalogenated with sodium formate in propan-2-ol using RhCl(PPh3)3 as the catalyst. The hydrogenolysis of 1,2,4-trichlorobenzene is selective to 1,2-dichlorobenzene, whereas the hydrogenolysis of 1,3- and 1,4-dichlorobenzene is sequential and selective according to the sequence: chlorobenzene > benzene.
Identifiersdoi: 10.1039/B102191P
issn: 1144-0546
e-issn: 1369-9261
Appears in Collections:(ICMA) Artículos
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