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Determination of the absolute configuration of 1,3,5-triphenyl-4,5- dihydropyrazole enantiomers by a combination of VCD, ECD measurements, and theoretical calculations

AuthorsVanthuyne, N.; Roussel, C.; Naubron, J.-V.; Jagerovic, Nadine ; Morales, Paula ; Alkorta, Ibon ; Elguero, José
Issue Date2011
PublisherPergamon Press
CitationTetrahedron Asymmetry 22: 1120- 1124 (2011)
AbstractThe enantiomers of 1,3,5-triphenyl-4,5-dihydropyrazole (an intense blue fluorescent compound) have been separated for the first time and their absolute configuration was established by a combination of VCD and ECD measurements and theoretical calculations. The enantiomers of 1,3,5-triphenyl-4,5-dihydropyrazole which are highly fluorescent both in solution (CH2Cl2) and in the solid state may find application in the very active field of enantioselective fluorosensors. © 2011 Elsevier Ltd. All rights reserved.
Publisher version (URL)http://dx.doi.org/10.1016/j.tetasy.2011.06.003
Identifiersdoi: 10.1016/j.tetasy.2011.06.003
issn: 0957-4166
Appears in Collections:(IQM) Artículos
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