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Title

Stereoselective formation of chiral metallopeptides

AuthorsRama, G.; Ardá, Ana ; Maréchal, J.D.; Gamba, I.; Ishida, J.; Jiménez-Barbero, Jesús ; Vázquez López, M.
KeywordsChirality
ligand effects
metallopeptides
molecular modeling
NMR spectroscopy
peptides
Issue Date4-Jun-2012
PublisherWiley-VCH
CitationChemistry - A European Journal, 18 (23) : 7030-7035 (2012)
AbstractPlaying into our hands: The achiral bipyridine amino acid fluorenylmethyloxycarbonyl 5-amino-3-oxapentanoic acid (Fmoc-O1PenBpy-OH) has been used for the solid-phase synthesis of metallopeptides. Circular dichroism, molecular modeling, and NMR spectroscopic studies show that the chirality of the resulting metal complexes in aqueous solution is determined, and can thus be controlled, by the stereochemistry of one proline residue in the loop between the two coordinating O1PenBpy residues
Description6 páginas, 4 figuras, 2 tablas, 2 esquemas -- PAGS nros. 7030-7035
Publisher version (URL)http://dx.doi.org/10.1002/chem.201201036
URIhttp://hdl.handle.net/10261/60343
DOI10.1002/chem.201201036
ISSN0947-6539
E-ISSN1521-3765
Appears in Collections:(CIB) Artículos
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