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Tris(triazolyl)triazine via Click-Chemistry: A C3 Electron-Deficient Core with Liquid Crystalline and Luminescent Properties

AuthorsBeltran, Eduardo; Serrano, José Luis; Sierra, Teresa; Giménez, Raquel
Issue Date2010
PublisherAmerican Chemical Society
CitationOrganic Letters 12(7): 1404-1407 (2010)
AbstractThe synthesis of a novel core based on tris(triazolyl)triazine has been accomplished by a one-pot procedure that combines a 3-fold deprotection of alkyne groups and “click chemistry” of the aromatic alkyne and azide precursors. The procedure is straightforward for the preparation of functional materials for organic electronics. Indeed, compounds with low reduction potential are obtained. These compounds also show liquid crystalline behavior, displaying columnar mesophases at room temperature, and are luminescent in the visible region both in solution and in thin films.
Description4 páginas, 2 figuras, 2 tablas, 1 esquema.
Publisher version (URL)http://dx.doi.org/10.1021/ol902900y
Appears in Collections:(ICMA) Artículos
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