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Title

Synthesis of d-arabinose-derived polyhydroxylated pyrrolidine, indolizidine and pyrrolizidine alkaloids. Total synthesis of hyacinthacine A2

AuthorsDelso, J. Ignacio; Tejero, Tomás ; Goti, Andrea; Merino, Pedro
KeywordsAlkaloids
Pyrrolidines
Nitrones
Issue DateFeb-2010
PublisherElsevier
CitationTetrahedron 66(6): 1220-1227 (2010)
AbstractSeveral new polyhydroxylated alkaloids including pyrrolidines with a long side chain and 3-(hydroxymethyl) indolizidines were prepared from a common nitrone easily obtained from d-arabinose. In addition, a total synthesis of hyacinthacine A2 has been achieved in five steps and 67.7% overall yield starting from the same d-arabino-derived nitrone. All synthesized compounds have a common structural feature consisting of a pyrrolidine ring with d-arabino configuration.
Description8 páginas, 3 figuras, 5 esquemas.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2009.12.030
URIhttp://hdl.handle.net/10261/55894
DOI10.1016/j.tet.2009.12.030
ISSN0040-4020
Appears in Collections:(ICMA) Artículos
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