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Spin delocalization in the molecular manganese tetra-helicate cluster: [Mn3L4](ClO4)2(H2O)2

AuthorsRodríguez-Blanco, C.; Rodríguez-Velamazán, J. A.; Campo, Javier ; Gillon, Béatrice; Sánchez Costa, J.; Gamez, Patrick; Luzón, Javier
Issue Date2011
PublisherInstitute of Physics Publishing
CitationJournal of Physics: Conference Series 325(1): 012009 (2011)
AbstractThe magnetic properties of the compound [Mn3L4](C1O4)2(H2O)2 revealed that it is a rare trinuclear MnII compound showing ferromagnetic interactions and a possible anisotropic behaviour. Here we report preliminary magnetic susceptibility measurements and spin density determinations at the Mn and O atoms to elucidate the magnetic interaction model and the possible anomalous anisotropic magnetic behaviour reported previously for this compound, that it is confirmed to be inexistent.
Identifiersdoi: 10.1088/1742-6596/325/1/012009
issn: 1742-6588
e-issn: 1742-6596
Appears in Collections:(ICMA) Artículos
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