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Solid-state and solution structure of a hypervalent AX 5 compound: Sb(C6F5)5

AuthorsGarcía-Monforte, M. Ángeles ; Alonso, Pablo J.; Ara, Irene ; Menjón, Babil ; Romero, Pilar
Issue Date2012
CitationAngewandte Chemie International Edition 51(11): 2754- 2757 (2012)
AbstractEliminating restraints: A trigonal-bipyramidal structure has been found to be the energetically favored geometry of the hypervalent AX 5 molecule Sb(C 6F 5) 5 in the solid state and also in fluid solution, where molecules move freely and no crystal packing effects operate (see picture).
Identifiersdoi: 10.1002/anie.201108858
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ICMA) Artículos
(ISQCH) Artículos
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