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Reversible insertion of aldehydes and ketones into Cp3--H bonds of chiral bis(oxazoline)/iridium complexes

AuthorsCastillo, María R.; Martín, Marta ; Fraile, José M. ; Mayoral, José A. ; Sola, Eduardo
Issue Date2011
CitationAngewandte Chemie International Edition 50(14): 3240-3243 (2011)
AbstractBOX of tricks: Facile, reversible, and diastereoselective functionalizations of methylene C-H bonds with carbonyl compounds have been observed within chiral bis(oxazoline)/iridium complexes (see structure; O-red, N-blue, P-orange, Ir-purple). These reactions are described and discussed together with the classic C-H oxidative additions to iridium that occur within these same compounds.
Identifiersdoi: 10.1002/anie.201007292
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ICMA) Artículos
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