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Recent advances in enantioselective organocatalyzed anhydride desymmetrization and its application to the synthesis of valuable enantiopure compounds  

AuthorsDíaz de Villegas, María D. ; Gálvez, José A. ; Etayo, Pablo; Badorrey, Ramón ; López-Ram-de-Víu, Pilar
Issue Date2011
PublisherRoyal Society of Chemistry (UK)
CitationChemical Society Reviews 40(11): 5564-5587 (2011)
AbstractRecent years have witnessed increasing interest in the field of asymmetric organocatalysis. In particular, efforts in this field have been devoted to the use of small organic molecules in asymmetric processes based on enantiotopic face discrimination and, only recently, efforts have also been devoted to asymmetric organocatalytic desymmetrization of prochiral substrates—a process based on enantiotopic group discrimination. This critical review documents the advances in the use of organocatalysis for the enantioselective desymmetrization of achiral and meso anhydrides and its application to the synthesis of valuable compounds as reported until 2010 (134 references).
Identifiersdoi: 10.1039/C1CS15120G
issn: 0306-0012
e-issn: 1460-4744
Appears in Collections:(ISQCH) Artículos
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