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Reactivity of unsaturated 5(4H)-oxazolones with Hg(II) acetate: Synthesis of methyl N-benzoylamino-3-arylacrylates

AuthorsRoiban, Gheorghe-Doru; Soler, Tatiana; Contel, María; Grosu, Ion; Cativiela, Carlos ; Urriolabeitia, Esteban P.
Issue Date2012
PublisherTaylor & Francis
CitationSynthetic Communications 42(2): 195-203 (2012)
AbstractAn efficient and high-yield procedure to prepare methyl N-benzoylamino-3-arylacrylates from unsaturated (Z)-2-aryl-4-arylidene-5-(4H)- oxazolones and Hg(OAc)2 in methanol is described herein. The observed reactivity of mercury(II) acetate here is different than its usual metallating behavior and it cleaves the unsaturated oxazolone ring without change of stereochemistry.
Identifiersdoi: 10.1080/00397911.2010.523157
issn: 0039-7911
e-issn: 1532-2432
Appears in Collections:(ICMA) Artículos
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