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dc.contributor.authorSánchez Costa, J.-
dc.contributor.authorRoubeau, Olivier-
dc.contributor.authorTeat, Simon J.-
dc.contributor.authorGamez, Patrick-
dc.contributor.authorReedijk, Jan-
dc.identifierdoi: 10.1039/C004478D-
dc.identifiere-issn: 1466-8033-
dc.identifier.citationCrystEngComm 12(10): 3057-3064 (2010)-
dc.description.abstractTwo new 1,3,5-triazine-based ligands, namely 2-chloro-4,6-bis-N-[2- methylsulfanyl-N-(pyridin-2-ylmethyl)aniline]-1,3,5-triazine (cspat) and 2,4,6-tris-N-[N-2-(methylsulfanyl)-N-(pyridin-2-ylmethyl)ethanamine]-1,3, 5-triazine (spet), have been purposely designed to favour anion-π and/or lone pair-π interactions in their coordination compounds. Three copper coordination compounds from these ligands, i.e. [Cu(cspat)Br2] (1), [Cu(cspat)(NO3)2] (2) and [Cu(Hspet)(NO3) 2](NO3)·0.5H2O (3), have been obtained and their single-crystal X-ray structures have been determined. As expected, the solid-state structures of the three CuII compounds are composed of supramolecular networks of anion-π and/or lone pair-π non-covalent bonds. © 2010 The Royal Society of Chemistry.-
dc.description.sponsorshipThis work has been supported financially by the Graduate Research School Combination ‘‘Catalysis’’, a joint activity of the graduate research schools NIOK, HRSMC, and PTN. The Spanish Ministerio de Ciencia through the Juan de la Cierva Program number 18-08-463B-750 is also acknowledged. The Advanced Light Source (SJT) is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under contract no. DE-AC02- 05CH11231. ##info:eu-repo/grantAgreement/EC/FP7/-
dc.publisherRoyal Society of Chemistry-
dc.titleProficiency of the electron-deficient 1,3,5-triazine ring to generate anion-π and lone pair-π interactions-
dc.description.versionPeer Reviewed-
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