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Proficiency of the electron-deficient 1,3,5-triazine ring to generate anion-π and lone pair-π interactions

AuthorsSánchez Costa, J.; Roubeau, Olivier; Teat, Simon J.; Gamez, Patrick; Reedijk, Jan
Issue Date2010
PublisherRoyal Society of Chemistry (UK)
CitationCrystEngComm 12(10): 3057-3064 (2010)
AbstractTwo new 1,3,5-triazine-based ligands, namely 2-chloro-4,6-bis-N-[2- methylsulfanyl-N-(pyridin-2-ylmethyl)aniline]-1,3,5-triazine (cspat) and 2,4,6-tris-N-[N-2-(methylsulfanyl)-N-(pyridin-2-ylmethyl)ethanamine]-1,3, 5-triazine (spet), have been purposely designed to favour anion-π and/or lone pair-π interactions in their coordination compounds. Three copper coordination compounds from these ligands, i.e. [Cu(cspat)Br2] (1), [Cu(cspat)(NO3)2] (2) and [Cu(Hspet)(NO3) 2](NO3)·0.5H2O (3), have been obtained and their single-crystal X-ray structures have been determined. As expected, the solid-state structures of the three CuII compounds are composed of supramolecular networks of anion-π and/or lone pair-π non-covalent bonds. © 2010 The Royal Society of Chemistry.
Identifiersdoi: 10.1039/C004478D
e-issn: 1466-8033
Appears in Collections:(ICMA) Artículos
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