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Multicomponent Synthesis of Pyran-2-ylidene Chromium(0) and Tungsten(0) Fischer Carbene Complexes

AuthorsBaeza, Beatriz; Oliván, Montserrat
Issue Date2010
PublisherAmerican Chemical Society
CitationOrganometallics 29(7): 1607-1611 (2010)
AbstractA new reaction between chromium(0) and tungsten(0) carbene complexes 1 and alkynyl esters or ketones 2 in the presence of NMO to yield pyran-2-ylidene complexes 3 has been explored. Here, we discuss the scope of the reaction and propose a plausible mechanistic pathway. The method is a new multicomponent approach for the synthesis of pyranylidene carbene complexes.
Identifiersdoi: 10.1021/om9009558
issn: 0276-7333
e-issn: 1520-6041
Appears in Collections:(ICMA) Artículos
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