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Title

Synthesis of a new stable and water-soluble tris(4-hydroxysulfonyltetrachlorophenyl)methyl radical with selective oxidative capacity

AuthorsMesa, Juan Antonio ; Velázquez-Palenzuela, Amado; Brillas, Enric; Torres, Josep Lluís ; Juliá, Lluís
KeywordsFree radical
Radical-scavenging
Chemosensor
Electron paramagnetic resonance
Issue Date2011
PublisherElsevier
CitationTetrahedron
AbstractA new stable organic free radical of the PTM (perchlorotriphenylmethyl) series very soluble in water is reported. This free radical is sensitive to electron transfer processes, and the selectivity of these reactions in the presence of ascorbic acid, pyrogallol, and catechol as reducing species is described. The electron paramagnetic resonance spectrum and the electrochemical behavior are also presented.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2011.02.069
URIhttp://hdl.handle.net/10261/53149
DOI10.1016/j.tet.2011.02.069
ISSN0040-4020
Appears in Collections:(IQAC) Artículos
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