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Laser control of zeolite nucleation

AuthorsNavarro, Marta ; Mayoral, Alvaro; Mateo, Ester; Lahoz, Ruth; Fuente, Germán F. de la; Coronas, Joaquín
Issue Date2012
CitationChemPhysChem 13(3): 736-740 (2012)
AbstractPrecursor solutions for the synthesis of zeolites are irradiated by means of a Nd-YAG laser. These solutions are subsequently submitted to a hydrothermal treatment and the results analyzed by X-ray diffraction and electron microscopy. Laser irradiation promotes the formation of silica nanoparticles that nucleate into zeolite (silicalite-1), following a hydrothermal treatment. The average crystal size (in the 0.6-3.6 οm range) of the zeolite exponentially decreases as a function of laser irradiation time. In addition, a longer irradiation time results in a narrower crystal size distribution.
Identifiersdoi: 10.1002/cphc.201100783
issn: 1439-4235
e-issn: 1439-7641
Appears in Collections:(ICMA) Artículos
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