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Título: | Highly ordered π-extended discotic liquid-crystalline triindoles |
Autor: | García-Frutos, Eva M. CSIC ORCID; Omenat, Ana CSIC ORCID; Barberá, Joaquín CSIC ORCID; Serrano, José Luis CSIC ORCID; Gómez-Lor, Berta CSIC ORCID | Fecha de publicación: | 2011 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry 21(19): 6831-6836 (2011) | Resumen: | New π-extended discotic liquid crystals based on heptacyclic triindole have been synthesized and their mesomorphic behaviour investigated. The synthesis of π-extended compounds was carried out by oxidative cyclodehydrogenation of differently substituted star-shaped hexaaryltriindoles to afford the planar derivatives with an extended core. Extending the conjugation in these materials results in a significant increase in the order and range of the mesophases. The influence of the peripherally attached groups in the mesomorphic and electronic properties offers a great opportunity to further tune the properties of these compounds intended to their incorporation in devices. © 2011 The Royal Society of Chemistry. | URI: | http://hdl.handle.net/10261/52812 | DOI: | 10.1039/C0JM04395H | Identificadores: | doi: 10.1039/C0JM04395H issn: 0959-9428 e-issn: 1364-5501 |
Aparece en las colecciones: | (ICMM) Artículos (ICMA) Artículos |
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