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dc.contributor.authorEscuer, A.-
dc.contributor.authorEsteban, Jordi-
dc.contributor.authorAliaga-Alcalde, N.-
dc.contributor.authorCalvet, Teresa-
dc.contributor.authorRoubeau, Olivier-
dc.contributor.authorTeat, Simon J.-
dc.date.accessioned2012-07-04T07:33:04Z-
dc.date.available2012-07-04T07:33:04Z-
dc.date.issued2010-
dc.identifierdoi: 10.1021/ic9020965-
dc.identifierissn: 0020-1669-
dc.identifiere-issn: 1520-510X-
dc.identifier.citationInorganic Chemistry 49(5): 2259-2266 (2010)-
dc.identifier.urihttp://hdl.handle.net/10261/52751-
dc.description.abstractIn the present work, coordination possibilities of the system dapdoH2/Ni2+, being dapdoH2 = 2,6-diacetylpyridine dioxime, have been explored, offering as a result a number of unprecedented clusters with a variety of topologies and magnetic behaviors. Depending on the precursors and reaction conditions, several compounds named [Ni2(dapdo)2] (1), [Ni3(OH)(BzO)3(dapdo)(dapdoH2)(H2O)]·1.25H2O (2), [Ni3(AcO)4(dapdoH)2(H2O)2]·H2O (3), and [Ni4(AcO)3(dapdo)(dapdoH)2(H2O)3]·(AcO)·3H2O (4) were achieved and structurally well-characterized. Dc magnetic measurements were carried out in the 2−300 K range revealing antiferromagnetic interactions for (2−4) compounds and diamagnetic response for the square planar coordinated complex (1).-
dc.description.sponsorshipThis work was supported by the CICYT Projects CTQ2009-07264.-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.rightsclosedAccess-
dc.titleFirst Structural and Magnetic Studies of Ni Clusters Containing 2,6-Diacetylpyridine-dioxime as a Ligand-
dc.typeartículo-
dc.identifier.doi10.1021/ic9020965-
dc.date.updated2012-07-04T07:33:05Z-
dc.description.versionPeer Reviewed-
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