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http://hdl.handle.net/10261/52677
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Marqués-López, Eugenia | - |
dc.contributor.author | Alcaine, Ana | - |
dc.contributor.author | Tejero, Tomás | - |
dc.contributor.author | Herrera, Raquel P. | - |
dc.date.accessioned | 2012-07-03T08:41:37Z | - |
dc.date.available | 2012-07-03T08:41:37Z | - |
dc.date.issued | 2011 | - |
dc.identifier | doi: 10.1002/ejoc.201100506 | - |
dc.identifier | issn: 1434-193X | - |
dc.identifier | e-issn: 1099-0690 | - |
dc.identifier.citation | European Journal of Organic Chemistry 20-21: 3700-3705 (2011) | - |
dc.identifier.uri | http://hdl.handle.net/10261/52677 | - |
dc.description.abstract | A novel study on the influence of external Brønsted acids on thiourea catalysts in the asymmetric Friedel–Crafts alkylation of indoles with nitroalkenes is reported. The final 3-substituted indole derivatives were synthesized with better results because of cooperative effects between the chiral thiourea and a Brønsted acid additive (1a·HA). The effects of diverse catalysts, different acid additives, solvents, and temperatures in the reaction were also explored. The high reactivity and selectivity of the reaction is presumptively attributed to an appropriate assembly between the Brønsted acid and the thiourea structure, affording a more acidic and rigid catalytic complex. | - |
dc.description.sponsorship | We thank the Ministry of Science and Innovation (MICINN), Madrid, Spain (Project CTQ2010-19606), and the Government of Aragón, Zaragoza, Spain (Project PI064/09 and Research Groups, E-10), for financial support of our research. E.M.-L. thanks CSIC for a JAE-Doc postdoctoral contract. | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | - |
dc.title | Enhanced Efficiency of Thiourea Catalysts by External Brønsted Acids in the Friedel–Crafts Alkylation of Indoles | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/ejoc.201100506 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/ejoc.201100506 | - |
dc.date.updated | 2012-07-03T08:41:37Z | - |
dc.description.version | Peer Reviewed | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.contributor.funder | Gobierno de Aragón | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100010067 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
Aparece en las colecciones: | (ISQCH) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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Enhanced Efficiency of Thiourea.pdf | 255,49 kB | Adobe PDF | Visualizar/Abrir |
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