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Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl) phenol (mqmpH) with several transition metal ions: Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes

AutorNayak, Sanjit; Roubeau, Olivier; Reedijk, Jan
Fecha de publicación2010
EditorElsevier
CitaciónPolyhedron 29(11): 2291-2296 (2010)
ResumenFour coordination compounds were synthesized in high yields from different transition metal ions (Fe III, Co II, and Cu II) and an in situ generated Schiff-baseligand, i.e.2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH). The compounds were characterized by single-crystal X-ray diffraction, ESI-MS, IR spectroscopy, and ligand-field spectroscopy. The iron(III) complex is an efficient catalyst for the oxidation of alkanes and alkenes, under relatively mild conditions and with dihydrogen peroxide as terminal oxidant.
URIhttp://hdl.handle.net/10261/52539
DOIj.poly.2010.04.035
Identificadoresdoi: j.poly.2010.04.035
issn: 0277-5387
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