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C-Branched chiral (racemic) macrocyclic amino acids: structure of their Ni(II), Zn(II) and Cu(II) complexes

AuthorsPellico, D.; Gómez-Gallego, Mar; Escudero, Rosa; Ramírez-López, Pedro; Oliván, Montserrat ; Sierra, Miguel A.
Issue Date2011
PublisherRoyal Society of Chemistry (Great Britain)
CitationDalton Transactions 40(36): 9145-9153 (2011)
AbstractA new procedure for the synthesis of macrocyclic embedded bis-α-amino acids and their use as cation-ligands is described. These compounds are able to form stable Cu(ii), Zn(ii) and Ni(ii) complexes as long as they have a flexible tether between the two nitrogen atoms. For a given macrocycle, the X-ray diffraction studies revealed diastereomerically pure complexes having different geometries depending on the metal ion. © 2011 The Royal Society of Chemistry.
Identifiersdoi: 10.1039/C1DT10539F
issn: 1477-9226
e-issn: 1477-9234
Appears in Collections:(ISQCH) Artículos
(IQOG) Artículos
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