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Título

A dinuclear gold(I)–silver(I) derivative of 2-cyclopentylidene-2-sulfanylacetic acid and related complexes: synthesis, crystal structures, properties and antitumor activity

AutorLaguna, Antonio ; López-de-Luzuriaga, José M.; Monge, Miguel
Fecha de publicación2011
EditorWiley-VCH
CitaciónEuropean Journal of Inorganic Chemistry 8: 1322-1332 (2011)
ResumenThe dinuclear complex [AgAu(PPh3)2cpa] (H2cpa = 2-cyclopentylidene-2-sulfanylacetic acid) was prepared by treating the precursor [Au(PPh3)(Hcpa)] with Ag(PPh3)NO3. The complex was characterised by spectroscopic methods (IR; 1H, 13C, 31P NMR) and mass spectrometry, and the structure was solved by a single-crystal X-ray diffraction study. Luminescence and theoretical studies were carried out, and the antitumor activity was studied in vitro against HeLa-229, A2780 and A2780cis cell lines. The related gold(I)–gold(I), [(AuPPh3)2cpa], and silver(I)–silver(I), [(AgPPh3)2cpa], compounds were also prepared and studied in the solid state and in solution.
Descripciónet al.
URIhttp://hdl.handle.net/10261/52171
DOI10.1002/ejic.201000959
Identificadoresdoi: 10.1002/ejic.201000959
issn: 1434-1948
e-issn: 1099-0682
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