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Título: | Shaping hybrid nanostructures with polymer matrices: the formation mechanism of silver–polypyrrole core/shell nanostructures |
Autor: | Muñoz Rojas, David CSIC ORCID; Oró, Judith CSIC ORCID; Ayyad, Omar CSIC ORCID; Gómez-Romero, P. CSIC ORCID | Fecha de publicación: | 2011 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry 21(7): 2078-2086 (2011) | Resumen: | The influence of experimental parameters in the formation of peculiar silver–polypyrrole core/shell nanostructures (Ag@PPy nanosnakes) has been studied in detail. Thus, the initial ratio of reactants and particle size, as well as the temperature, solvent and atmosphere used, all have a dramatic effect on the reaction outcome. From all these experiments and a careful investigation of the initial stages of reaction, the formation mechanism of such nanostructures has been proposed. The results presented show that the formation of a polypyrrole matrix around the initial Ag2O particles is key for the formation of Ag@PPy nanosnakes. Finally, the stability and time evolution of the hybrid nanosnakes are also reported. | Descripción: | 9 páginas, 9 figuras. | Versión del editor: | http://dx.doi.org/10.1039/C0JM01449D | URI: | http://hdl.handle.net/10261/48894 | DOI: | 10.1039/C0JM01449D | ISSN: | 0959-9428 | E-ISSN: | 1364-5501 |
Aparece en las colecciones: | (ICMAB) Artículos (CIN2) Artículos |
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