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Tunable symmetry and periodicity in binary supramolecular nanostructures

AuthorsOteyza, D. G. de ; Barrena, Esther ; Dosch, Helmut; Ortega, J. Enrique ; Wakayama, Yutaka
Issue Date2011
PublisherRoyal Society of Chemistry (UK)
CitationPhysical Chemistry Chemical Physics 13(10): 4220-4223 (2011)
AbstractWe present a route to change the “compositional” order of highly crystalline binary layers comprising diindenoperylene and copper-phthalocyanines from two- to one-dimensional periodicity. This is achieved by exchanging fluorine with hydrogen atoms in the phthalocyanines, thereby reducing the C–F***H–C interactions and allowing the interplay of long-range electrostatic interactions in mesoscopic phases. Linear patterns are thus obtained, whose periodicity can be additionally tuned by an appropriate stoichiometry of the components.
Description4 páginas, 3 figuras, 1 tabla.-- El pdf es la versión post-print del artículo.
Publisher version (URL)http://dx.doi.org/10.1039/C0CP02388D
Appears in Collections:(CFM) Artículos
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