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dc.contributor.authorRoces, Laura-
dc.contributor.authorGarcía-Granda, Santiago-
dc.date.accessioned2012-01-02T11:32:49Z-
dc.date.available2012-01-02T11:32:49Z-
dc.date.issued2010-
dc.identifier.citationOrganic Letters 12(3): 428-431 (2010)es_ES
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10261/43872-
dc.description4 páginas, 2 tablas, 4 esquemas.-- et al.es_ES
dc.description.abstractAsymmetric ortho-lithiation of N-dialkyl-P,P-diphenylphosphinamides using [n-BuLi·(−)-sparteine] is described as an efficient method for the synthesis of P-chiral ortho-functionalized derivatives in high yields and ee’s from 45 to >99%. The method allows access to new enantiomerically pure P-chiral phosphine and diimine ligands.es_ES
dc.description.sponsorshipWe thank the Ministerio de Ciencia e Innovación (project no. CTQ2008-117BQU) for financial support. I.F. thanks the Ramón y Cajal program for financial support.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.rightsclosedAccesses_ES
dc.titleEnantioselective desymmetrization of diphenylphosphinamides via (−)-sparteine-mediated ortho-Lithiation. Synthesis of P-Chiral ligandses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1021/ol902545q-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1021/ol902545qes_ES
dc.identifier.e-issn1523-7052-
dc.contributor.funderMinisterio de Ciencia e Innovación (España)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004837es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
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