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Título: | One-Pot Conversion of Proline Derivatives into Iodinated Iminosugar-Based Nucleosides, Useful Precursors of Highly Functionalized Nucleoside Analogues |
Autor: | Boto, Alicia CSIC ORCID ; Hernández, Dácil CSIC ORCID ; Hernández, Rosendo CSIC | Palabras clave: | Radical reactions Amino acids Nucleosides Nitrogen heterocycles Sequential processes |
Fecha de publicación: | dic-2010 | Editor: | Wiley-VCH | Citación: | European Journal of Organic Chemistry 34: 6633-6642 (2010) | Resumen: | Readily available proline derivatives can be transformed in one step into β-iodinated iminosugar-based nucleosides, under very mild conditions. The method couples a tandem radical decarboxylation–oxidation–β-iodination to the addition of nitrogen bases. The iodo group is introduced into the previously unfunctionalized 3-position. The resultant β-iodo derivatives are useful precursors of highly functionalizednucleoside analogues. | Descripción: | 1o páginas, 1 figura, 8 esquemas. | Versión del editor: | http://dx.doi.org/10.1002/ejoc.201000997 | URI: | http://hdl.handle.net/10261/39097 | DOI: | 10.1002/ejoc.201000997 | ISSN: | 1434-193X | E-ISSN: | 1099-0690 |
Aparece en las colecciones: | (IPNA) Artículos |
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