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Title

Crystal structures of self-assembled nanotubes from flexible macrocycles by weak interactions

AuthorsCarrillo Fumero, Romen ; López Rodríguez, Matías; Martín, Víctor S.; Martín, Tomás
Issue Date2010
PublisherRoyal Society of Chemistry (UK)
CitationCrystengcomm 12(11): 3676-3683 (2010)
AbstractHerein we report the crystal structures of tubular self-assemblies of flexible macrooligolides. The assembly is driven by the propensity of the macrocycles to create nearly flat structures displaying a void space within them and the cooperativity of weak directional interactions such as dipole–dipole interactions and CH***Ohydrogen bonds and non-directional interactions such as van der Waals contacts. The significance of the stereochemistry and the size of the cavity in the formation of the nanotubes are also studied.
Description8 páginas, 7 figuras, 2 tablas, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1039/C001261K
URIhttp://hdl.handle.net/10261/38649
DOIhttp://dx.doi.org/10.1039/C001261K
ISSN1466-8033
Appears in Collections:(IPNA) Artículos
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