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Título: | Crystal structures of self-assembled nanotubes from flexible macrocycles by weak interactions |
Autor: | Carrillo Fumero, Romen CSIC ORCID ; López Rodríguez, Matías; Martín, Víctor S. CSIC ORCID; Martín, Tomás CSIC ORCID | Fecha de publicación: | 2010 | Editor: | Royal Society of Chemistry (UK) | Citación: | Crystengcomm 12(11): 3676-3683 (2010) | Resumen: | Herein we report the crystal structures of tubular self-assemblies of flexible macrooligolides. The assembly is driven by the propensity of the macrocycles to create nearly flat structures displaying a void space within them and the cooperativity of weak directional interactions such as dipole–dipole interactions and CH***Ohydrogen bonds and non-directional interactions such as van der Waals contacts. The significance of the stereochemistry and the size of the cavity in the formation of the nanotubes are also studied. | Descripción: | 8 páginas, 7 figuras, 2 tablas, 2 esquemas. | Versión del editor: | http://dx.doi.org/10.1039/C001261K | URI: | http://hdl.handle.net/10261/38649 | DOI: | 10.1039/C001261K | ISSN: | 1466-8033 |
Aparece en las colecciones: | (IPNA) Artículos |
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ARTICULOS296182[1].pdf | 451,33 kB | Adobe PDF | Visualizar/Abrir |
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