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Title

Approach to the study of C-glycosyl flavones acylated with aliphatic and aromatic acids from Spergularia rubra by high-performance liquid chromatography-photodiode array detection/electrospray ionization multi-stage mass spectrometry

AuthorsFerreres, Federico ; Gil-Izquierdo, Ángel ; Vinholes, Juliana; Grosso, Clara; Valentão, Patricia; Andrade, Paula B.
Issue DateMar-2011
PublisherWiley-Blackwell
CitationRapid Communications in Mass Spectrometry 25(6): 700-712 (2011)
AbstractThe use of mass spectrometry (MS) coupled to liquid chromatography (LC) as working tool for the study of the C-glycosyl flavones acylated with aliphatic and aromatic acids has allowed the tentative characterization of these compounds in Spergularia rubra and the establishment of the position of the acylation on the sugar moiety of the C-glycosylation by use of MS data. The combination of retention time (Rt), ultraviolet (UV) and MSn data of the compounds revealed their C-glycosyl flavone nature, being luteolin, apigenin and chrysoeriol derivatives. Ten non-acylated flavones were identified, from which six are described for the first time (one 7-O-glycosyl-6,8-diC-glycosyl flavone, four 6,8-diC-glycosyl flavones and one 2”-O-glycosyl-6-C-glycosyl flavone). Twenty-six acylated derivatives were also found for the first time. These compounds are grouped in three classes, namely, C-glycosyl flavones acylated with aliphatic acids, with aromatic acids or with a mixed acylation. The first group is characterized by the presence of one 6,8-diC-(acetyl)glycosyl flavone, four 6,8-diC-(malonyl)glycosyl flavones and two 7-O-glycosyl-6,8-diC-(malonyl)glycosyl flavones, while in the second one twelve 6,8-diC-(acyl)glycosyl flavones and two 7-O-glycosyl-6,8-diC-(acyl)glycosyl flavones are described. The last class contained five 6,8-diC-(malonyl,acyl)glycosyl flavones. No previous work has described the presence of C-glycosyl flavones acylated with aliphatic acids in this genus.
Description13 páginas, 4 figuras, 4 tablas, 3 esquemas.
Publisher version (URL)http://dx.doi.org/10.1002/rcm.4910
URIhttp://hdl.handle.net/10261/38482
DOIhttp://dx.doi.org/10.1002/rcm.4910
ISSN0951-4198
Appears in Collections:(CEBAS) Artículos
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