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Indenyl–ruthenium(II) allenylidene complexes containing terpenic substituents as precursors of optically active terminal alkynes: scope and limitations

AuthorsCadierno, Victorio; Conejero, Salvador ; Gamasa, María Pilar; Gimeno, José
KeywordsAllenylidene complex
Issue Date23-Jul-2003
PublisherRoyal Society of Chemistry (Great Britain)
CitationDalton Transactions (15) : 3060-3066 (2003)
AbstractThe optically active allenylidene complex [Ru{ C C C(C9H16)}(η5-C9H7)(PPh3)2][PF6] (C(C9H16) = (1R,4S)-1,3,3-trimethyl-bicyclo[2.2.1]hept-2-ylidene) 1 regio- and stereoselectively reacts with unhindered anionic nucleophiles to yield the neutral σ-alkynyl derivatives [Ru{C CC(C9H16)R}(η5-C9H7)(PPh3)2] (R = H 2a, C N 2b, Me 2c, C CPh 2d). Protonation of 2a–d with HBF4·Et2O affords the cationic vinylidene complexes [Ru{ C C(H)C(C9H16)R}(η5-C9H7)(PPh3)2][BF4] 3a–d, which can be easily demetalated, by treatment with acetonitrile, yielding the corresponding chiral acetylenic compounds HC C(C9H16)R 4a–d. The novel optically active indenyl–ruthenium(II) allenylidene complexes [Ru{ C C C(C9H16)}(η5-C9H7)(PPh3)2][PF6] (C(C9H16) = (1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-ylidene) 9 and [Ru{ C C C(C9H14)}(η5-C9H7)(PPh3)2][PF6] (C(C9H14) = (1S,5S)-4,6,6-trimethyl-bicyclo[3.1.1]hept-3-en-2-ylidene) 10 have been prepared by activation of propargylic alcohols derived from the natural ketones (+)-camphor and (−)-verbenone, respectively, with [RuCl(η5-C9H7)(PPh3)2] 6. Treatment of 9 with anionic nucleophiles generates the neutral σ-enynyl complex [Ru{C CC(C9H15)}(η5-C9H7)(PPh3)2] 11 (C(C9H15) = (1R,4R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-en-2-yl).
Description7 páginas, 1 figura, esquemas.
Publisher version (URL)http://dx.doi.org/10.1039/B305608B
Appears in Collections:(IIQ) Artículos
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