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Title

Unexpected coupling between an η5-indenyl ligand and alkenyl-vinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(II) metallacycles

AuthorsCadierno, Victorio; Conejero, Salvador ; Díez, Josefina; Gamasa, María Pilar; Gimeno, José; García-Granda, Santiago
KeywordsTransition-metal
Allenylidene complexes
Organic synthesis
Metallacycles
Carbozyclyzation
η5-indenyl
alkenyl-vinylidene
Issue Date28-Feb-2003
PublisherRoyal Society of Chemistry (Great Britain)
CitationChemical Communications (7): 840-841 (2003)
AbstractVinylidene complexes [Ru{=C=C(H)CR1R2CH2C(Me)=CH2}(η5-C9H7)(PPh3)2][BF4] undergo an intramolecular coupling between the alkenyl-vinylidene fragment and the η5-indenyl ligand to afford indene-metallacyclic compounds (6a,b) in which the resulting functionalised indene group is η6-coordinated to the metal.
Description2 páginas, 1 figura, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1039/B212406H
URIhttp://hdl.handle.net/10261/37960
DOI10.1039/B212406H
ISSN1359-7345
Appears in Collections:(IIQ) Artículos
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