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Persistent (Amino)(Silyl)Carbenes

AuthorsCanac, Yves; Conejero, Salvador ; Donnadieu, Bruno; Schoeller, Wolfgand W.; Bertrand, Guy
Transition-metal complexes
Metal center
Issue Date27-Apr-2005
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 127(20): 7312-7313 (2005)
Abstract(Amino)(silyl)carbenes, prepared by substitution reactions at a carbene center, can survive several days at 0 °C. These species are not push−pull carbenes as their phosphino analogues and therefore are excellent ligands for transition-metal centers.
Description2 páginas, 3 figuras, 1 tabla, 2 esquemas.
Publisher version (URL)http://dx.doi.org/10.1021/ja051109f
Appears in Collections:(IIQ) Artículos
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