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dc.contributor.authorVargas Rodríguez, Sergio-
dc.contributor.authorRubio Moreno, Miguel-
dc.contributor.authorSuárez, Andrés-
dc.contributor.authorPizzano, Antonio-
dc.date.accessioned2011-07-21T07:11:42Z-
dc.date.available2011-07-21T07:11:42Z-
dc.date.issued2005-02-11-
dc.identifier.citationTetrahedron Letters 46(12): 2049-2052 (2005)es_ES
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10261/37883-
dc.description4 páginas, 2 tablas, esquemas. Corrigendum http://dx.doi.org/10.1016/j.tetlet.2005.11.040 Tetrahedron Letters 47(4): 615 (2006)es_ES
dc.description.abstractChiral phosphine–phosphites provide an alternative class of ligands for the iridium catalyzed enantioselective hydrogenation of imines. Optimization of ligand structure has afforded enantioselectivities up to 84% ee in the reduction of N-aryl imines. A significant influence of backbone nature on enantioselectivity has also been observed.es_ES
dc.description.sponsorshipWe gratefully acknowledge Ministerio de Educación y Ciencia for financial support (BQU-2000-1167). S.G. and M.R. thank CSIC (I3P Program) and Ministerio de Educación y Ciencia (FPU Program), respectively, for fellowships.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.rightsclosedAccesses_ES
dc.subjectAsymmetric hydrogenationes_ES
dc.subjectChiral amineses_ES
dc.subjectPhosphine-phosphiteses_ES
dc.titleAsymmetric hydrogenation of imines catalyzed by iridium complexes with phosphine–phosphite ligands: importance of backbone flexibilityes_ES
dc.typeartículoes_ES
dc.identifier.doi10.1016/j.tetlet.2005.01.144-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.tetlet.2005.01.144es_ES
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